The investigation of synthesis and textured properties of in situ formed hBN with spark plasma sintering

Abstract

Hexagonal boron nitride (hBN) exhibits high thermal conductivity within the in -plane direction and significantly lower thermal conductivity in the cross -plane direction because of its anisotropic nature. When the texture properties of bulk hBN are strong, it is a potentially promising application area for the insulating heat spreaders and heat sinks. In this study, hBN was synthesized in situ with the spark plasma sintering (SPS) technique and the effects of sintering temperature on the orientation of hBN grains were investigated. The precursor was prepared by chemically reacting urea and boric acid in heat treatment at 850 degrees C. The hBN was produced using the previous precursor in a SPS at 1500, 1700, and 1900 degrees C. The samples were characterized using XRD, FTIR, SEM and Raman spectroscopy. The properties of the samples were further determined through measurements of density, DSC and thermal diffusivity. The hBN samples obtained through the SPS process have nano and micron -size grains. The hBN was highly crystalline and homogeneous, as determined by the XRD pattern, Raman spectra and Raman maps. The orientation of hBN grains has been revealed in the c -axis of hBN crystallites and was preferably arranged within a plane parallel to the SPS pressing direction. The hBN orientation preference index (IOP) value of -19925.5 at 1700 degrees C indicates the highest quality texture orientation. Increasing the temperature to 1900 degrees C decreased the orientation in the direction parallel to the pressing direction. The highest thermal conductivity calculated according to the thermal diffusivity perpendicular to the sintering pressure direction was 8.86 W m- 1K-1 at 1900 degrees C.