Easily Accessible Rare-Earth-Containing Phosphonium Room-Temperature Ionic Liquids: EXAFS, Luminescence, and Magnetic Properties

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dc.authoridDandil, Sahra/0000-0001-9724-5597
dc.authoridSrinivasan, Geetha/0000-0002-3245-1012
dc.authoridFelton, Solveig/0000-0002-4552-2123
dc.authoridKaczmarek, Anna/0000-0001-5254-8762
dc.authoridBanerjee, Dipanjan/0000-0002-1933-8066
dc.authoridNockemann, Peter/0000-0001-9864-9702
dc.contributor.authorAlvarez-Vicente, Jorge
dc.contributor.authorDandil, Sahra
dc.contributor.authorBanerjee, Dipanjan
dc.contributor.authorGunaratne, H. Q. Nimal
dc.contributor.authorGray, Suzanne
dc.contributor.authorFelton, Solveig
dc.contributor.authorSrinivasan, Geetha
dc.date.accessioned2025-05-20T18:57:49Z
dc.date.issued2016
dc.departmentBilecik Şeyh Edebali Üniversitesi
dc.description.abstractA range of liquid rare earth chlorometallate complexes, with the alkyl-phosphoniuni cation, [P-666 14](+), has been synthesized and characterized. EXAFS Confirmed the predominant liquid-state speciation of the [LnCl(6)](3-) ion in the series with Ln = Nd, Eu, Dy. The crystal structure of the shorter-alkyl-chain cation analogue [P-4444](+) has been determined and exhibits a very large unit cell. The luminescence properties, with visible-light emissions of the liquid Tb, Eu, Pr, and Sm and the NIR emissions for the Nd and Er compounds, were determined. The effective magnetie moments were measured and fitted for the Nd, Tb, Ho, Dy, Gd, and Er samples.
dc.description.sponsorshipRoyal Society [RG130739]; Seagate Technology (Ireland); Hercules Foundation [AUGE/09/024]; Ghent University's Special Research Fund (BOF) [BOF15/PDO/091]; EPSRC
dc.description.sponsorshipP.N. and S.F. thank the Royal Society for a Research Grant (RG130739). We thank Seagate Technology (Ireland) for their financial support to establish ANSIN (www.ansin.eu). R.V.D. thanks the Hercules Foundation (project AUGE/09/024 Advanced Luminescence Setup) for funding. A.M.K. acknowledges Ghent University's Special Research Fund (BOF) for a Postdoctoral Mandate (project BOF15/PDO/091). We thank the FWO-Vlaanderen and The Netherlands Organisation for Scientific Research (NWO) for providing beam time at the Dutch - Belgian Beamline (DUBBLE, BM26A, ESRF). Matthias Groh and Alexander Wolff from TU Dresden are acknowledged for help with crystal data collection. S.G. acknowledges a doctoral training account Ph.D. studentship from EPSRC. We thank Jeff Dyck, Eamonn Conrad, Michael Moser, and the team at CYTEC for all their support and abundance of phosphonium ionic liquid supplies.
dc.identifier.doi10.1021/acs.jpcb.6b03870
dc.identifier.endpage5311
dc.identifier.issn1520-6106
dc.identifier.issue23
dc.identifier.pmid27203286
dc.identifier.scopus2-s2.0-84975230139
dc.identifier.scopusqualityQ2
dc.identifier.startpage5301
dc.identifier.urihttps://doi.org/10.1021/acs.jpcb.6b03870
dc.identifier.urihttps://hdl.handle.net/11552/7962
dc.identifier.volume120
dc.identifier.wosWOS:000378194900019
dc.identifier.wosqualityQ3
dc.indekslendigikaynakWoS
dc.indekslendigikaynakScopus
dc.indekslendigikaynakPubMed
dc.indekslendigikaynakWoS - Science Citation Index Expanded
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.ispartofJournal of Physical Chemistry B
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı
dc.rightsinfo:eu-repo/semantics/openAccess
dc.snmzKA_WOS_20250518
dc.subjectLanthanum
dc.subjectChloride
dc.subjectCoordination
dc.subjectSpeciation
dc.subjectComplexes
dc.titleEasily Accessible Rare-Earth-Containing Phosphonium Room-Temperature Ionic Liquids: EXAFS, Luminescence, and Magnetic Properties
dc.typeArticle

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