Tailoring Cu/Al2O3 catalysts for the catalytic pyrolysis of tomato waste

Abstract

In this study, pyrolysis of tomato waste has been performed in fixed bed tubular reactor at 500 degrees C, both in absence and presence of Cu/Al2O3 catalyst. The influences of heating rate, catalyst preparation method and catalyst loading on bio-oil yields and properties were examined. According to pyrolysis experiments, the highest bio-oil yield was obtained as 30.31% with a heating rate of 100 degrees C/min, 5% Cu/Al2O3 catalyst loading ratio and co-precipitation method. Results showed that the catalysts have strong positive effect on bio-oil yields. Bio-oil quality obtained from fast catalytic pyrolysis was more favorable than that obtained from non-catalytic and slow catalytic pyrolysis. (C) 2017 Energy Institute. Published by Elsevier Ltd. All rights reserved.